The kinetics and mechanism of filiform corrosion affecting organic coated Mg alloy surfaces

نویسندگان

چکیده

The filiform corrosion (FFC) of organic coated magnesium alloys is investigated using in-situ scanning Kelvin probe and time-lapse photography. FFC initiated by injecting MgCl2, HCl FeCl2 into a coating defect ensuing propagation rates are shown to increase as logarithmic function the chloride ion concentration strongly dependent on relative humidity. Post-corrosion surface analysis shows abundance near filament leading edge evidence sequestration within corroded regions behind. mechanism consistent with chloride-induced anodic dissolution at front coupling water reduction cathodically-activated

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ژورنال

عنوان ژورنال: Corrosion Science

سال: 2022

ISSN: ['1879-0496', '0010-938X']

DOI: https://doi.org/10.1016/j.corsci.2022.110477